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Beilstein J. Org. Chem. 2020, 16, 492–501, doi:10.3762/bjoc.16.44
Graphical Abstract
Scheme 1: Comparison of different ring-opening reactions of 2-oxazolines and thiazolidinones synthesis.
Scheme 2: KOt-Bu-promoted selective ring-opening N-alkylation of 2-methyl-2-oxazoline with benzyl bromides. C...
Scheme 3: KOt-Bu-promoted selective ring-opening N-alkylation of 2-methyl-2-oxazoline with benzyl chlorides. ...
Scheme 4: KOt-Bu-promoted selective ring-opening N-alkylation of 2,4,4-trimethyl-4,5-dihydrooxazole (2b) with...
Scheme 5: KOt-Bu/I2-promoted selective N-alkylation to synthesis of thiazolidone derivatives. Conditions: KOt...
Scheme 6: Transformation of 2-aminoethyl acetate derivative to 2-(dibenzylamino)ethanol.
Scheme 7: Control experiments and 18O-labeling experiment.
Scheme 8: Control experiments with radical scavengers.
Scheme 9: Proposed mechanism.
Beilstein J. Org. Chem. 2014, 10, 2886–2891, doi:10.3762/bjoc.10.305
Scheme 1: Synthetic approaches to benzo[b]furans from 2-alkynylphenols, ketones and 2-fluorophenylacetylene d...
Scheme 2: Copper-promoted reaction of 2-fluorophenylacetylene derivatives to yield benzo[b]furans. Reaction c...
Scheme 3: Copper-promoted synthesis of 2,2'-bisbenzofuran derivatives.
Scheme 4: Intramolecular competition experiments.
Scheme 5: Copper-promoted synthesis of benzo[b]thiophenes.
Scheme 6: Proposed mechanism for the annulation reaction.
Beilstein J. Org. Chem. 2012, 8, 61–70, doi:10.3762/bjoc.8.6
Scheme 1: The proposed process for the formation of N-phenyl isothiocyanate from aniline.